Assessments - 3, GPA: 4
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C (closed cup in accordance with ASTM D3278) Extinguishing Media: Dry chemical or carbon dioxide Fire Fighting Instructions: Breathing apparatus required. No special explosive hazards are known. 6. Accidental Release Measures Shut off ignition sources. If a spill occurs, use sponges to wipe-up toner, then rinse area with damp cloth. Place waste in closed container for disposal. Use proper ventilation. Do not dispose of waste to the sewer. No eye or skin protection required during clean-up. Wash hands with soap and water. 7. Precautions for Safe Handling and Use Keep out of reach of children and do not dismantle or incinerate cartridge. Keep cartridge in dark, cool, dry, and well ventilated are. Do not store cartridges with oxidizing agents. Make sure cartridge is dry before insertion into printer housing. Avoid dispersing toner. 8. Exposure Controls and Personal Protection Engineering Controls: None required when cartridges are used as intended Exposure Controls: None required when cartridges are used as intended. Otherwise, ACGIH TLV (2003): 10mg/cubic meter (total) 3mg/cubic meter (respiratory) Personal Protection: None required when cartridges are used as intended 9. Physical and Chemical Properties of Toner Formulation Appearance: Moist Yellow Powder Odor: Slight pH: Organically neutral Boiling point: Not applicable Freezing point: Not applicable Softening point: 120 – 130 deg. C Flash point: >230 deg. F / 110 deg. C (CC) Auto flammability: Over 300 deg. C Explosive properties: None Oxidizing properties: None Vapor density: Not applicable Relative density: 1.12 at 68 deg. F / 20 deg. C Solubility in water: Negligible Solubility in fat: No data available Partition coefficient: No data available Viscosity: Less than 5mPa-s 10. Stability and Reactivity Stability: Stable Hazardous polymerization: Will not occur Hazard decomposition products: None Incompatible materials: Oxidizers and explosives 11. Toxicology and Health Hazards Routes Of Overexposure: Eye, skin, inhalation, and oral Acute Health Hazards: . Overexposure of eye surface to toner may be mildly irritating . Overexposure of skin to toner contact may cause irritation and in some people swelling and redness . Intentional inhalation overexposure to toner may result in respiratory tract irritation . Intentional or accidental oral ingestion may cause an upset stomach Chronic Health Hazards: Use of this product, as intended, does not result in inhalation of fugitive excessive dust. In an inhalation study with rats chronically exposed to a typical developer, a mild to moderate degree of lung fibrosis was observed in approximately 90% of rats in the high concentration exposure group (16mg/cubic meter), and a minimal to mid degree of fibrosis was noted in approximately 20% of the animal in the middle exposure group (4mg/cubic meter). But no pulmonary change was reported in the lowest exposure group (1mg/cubic meter), the most relevant level to potential human exposure. Carcinogenicity: With excessive exposure, carbon black has been listed as a possible human carcinogen. However, as engineered within this toner cartridge, emissions to air of carbon black during normal printing use has not been found. IARC, the International Agency for Research on Cancer, has found printing toners to be not classifiable as human carcinogens. Titanium dioxide is classified as “possibly carcinogenic to humans” (Group 2B). In animal chronic inhalation studies, the tumor formulation observed in only rats with animal chronic inhalation is attributed to “lung overloading”, a generic response to excessive amounts of any dust retained in the lungs for a prolonged interval. Use of this product, as intended, does not result in inhalation of excessive dust. Epidemiological studies to date have not revealed any evidence of the relation between exposure to titanium dioxide and diseases of the respiratory tract beyond the general effects of dust. Toxicity Data: Oral LD50 Dermal LD50 Inhalant LC50 OSHA Regulated? >5000mg/kg(Rats) >5000mg/kg(Rats) 4.1mg/L/4hr(Rat) Not Established 12. Ecological Information Acute Toxicity: 96hr LC 50: >500 mg/L (practically non-toxic) 48hr EC 50 (Daphnia magma): >100 mg/L (practically non-toxic) 13. Disposal Considerations Used and unused cartridges are not a federal RCRA hazardous waste. Disposal should be in accordance with federal, state, and local requirements. 14. Transportation Information Not regulated as a Hazardous Material by DOT, IMO, or IATA 15. Regulatory Considerations U.S. DOT Hazard Class Regulated? No U.S. OSHA Inhalation Hazard? No In U.S., NFPA/HMIS Hazard Rating: Health (1), Flammability (1), Instability/Reactivity (0), Other (0) EU RoHS compliant? Yes California Proposition 65: Yes, titanium dioxide (CAS# 13463-67-7) as <1.0% by weight of toner formulation 16. Other Information This PIS adheres to U.S. regulatory requirements and standards and may not meet the regulatory requirements in other locations. This is a revised Product Informa...